Neodymium doped Gadolinium Vanadate (Nd:GdVO4) is a promising material for diode pumped laser. Similar to Nd:YVO4 crystal, Nd:GdVO4 crystal also exhibits high gain, low threshold, and high absorption coefficients at pumping wavelengths, which result from the excellent fit of the neodymium dopant in the crystal lattice. Nd:GdVO4 has the additional advantage over Nd:YVO4 of a much higher thermal conductivity. With advanced technology on growing and manufacturing high optical quality Nd:GdVO4 crystals, FOCtek can provide a wide variety of finished crystals, our general Nd:GdVO4 production capabilities include.

 

 Capabilities Include:

1)
Nd dopant concentration: 0.2---3.0 atm%
2)
Dopant tolerance: within 10% of concentration.
3)
Width X Height: 1X1 ~ 16X16 mm
4)
Length: 0.02 ~ 20mm

 

Typical Sepecification and Tolerance:
1)
Orientation:
a-cut crystalline direction(+/-0.20)
2)
Dimensional tolerance:
+/-0.1mm(typical)High precision +/-0.005mm can be available upon request.
3)
Wavefront Distortion:
<l/8@633nm
4)
Surface quality:
better than 20/10 Scratch/Dig per MIL-O-1380A
5)
Parallelism:
< 10 arc seconds
6)
Perpendicularity:
< 5 arc minutes
7)
Surface flatness:
<l/10 at 632.8nm
8)
Clear aperture:
Central 95%
9)
Chamfer:
0.15x450
10)
Damage threshold:
over 15J/cm2 (rods without coating) over 700 MW/cm2 (coated)
11)
Coating:
1)AR@1063nm, R< 0.1% & HT@808nm, T>95%(see coating 3-1 )
2)HR@1063nm, R>99.8% & HT@808nm, T>95%(see coating 3-2 )
3)AR@1063 nm, R<0.1%(see coating 3-3 )

 

Notes:
To inquiry or order a finished Nd:GdVO4 laser crystals, please specify the specification listed above, for common online_ordering, we only need to know the main specification: Nd-dopant concentration, sizes, surface quality and coating. For special request, please specify specification in details for evaluation and fabrication.
Physical and Optical Properties
Crystal Structure
Zircon Tetragonal, space group D4h, a=b=7.21, c=6.35
Melting Point
1780°C
Density
5.47g/ cm3
Mohs Hardness
Glass-like, ~ 5
Thermal Expansion Coefficient
aa=1.5x10-6/K, ac=7.3x10-6/K
Thermal Conductivity Coefficient
11.7 W/m/K <110>
Peak Absorption Wavelength
808.5 nm
Lasing Wavelength
912.6 nm, 1063.1 nm, 1341.3 nm
Crystal Class
Positive uniaxial, no=na=nb  ne=n  
no=1.9854, ne=2.1981,@ 1064nm
no=2.0382, ne=2.2929, @ 532nm
no=1.9977, ne=2.2198, @ 808nm
Thermal Optical Coefficient
dn/dT=4.7x10-6/K
Stimulated Emission Cross-Section
7.60x10-19cm2 @1064 nm
Fluorescent LifetimeNd=1.2 atm%
95 μs@ 808 nm
Loss Coefficient
0.003 cm-1@ 1064 nm
Absorption CoefficienceNd=1.2 atm%
74 cm-1 @ 808 nm
Absorption LengthNd=1.2 atm%
0.18 mm @ 808 nm
Intrinsic LossNd=1.2 atm%
Less 0.1% cm-1 @1064 nm
Line width
0.6 nm
Polarized Laser Emission
p parallel to optic axis (c-axis)
Diode Pumped Optical to Optical Efficiency
> 60%
Sellmeier Equation (for pure GdVO4 crystals)
ne2=4.734369 + 0.1216149/(l2 - 0.0523664) - 0.013927l2no2=3.8987165+0.05990622/(l- 0.0514395) - 0.011319l2

Nd:GdVO4 properties compare with Nd:YVO4 
 
-
Nd:GdVO4, 1.2 atm% Nd
Nd:YVO4 1.1 atm% Nd
Melting temperature (T°C)
1780
1825
Fluorescence lifetime ( t )
95 μs
100 μs
Stimulated emission cross section ( s ) 7.6x10 -19 cm -2 15.6x10 -19 cm -2 ( p -pol)
Absorption coefficient
78cm -1 31.2 cm -1
La 0.18mm 0.32mm
Threshold power 70mw 78mw
Conversion efficiency h s 50% 48.6%
Thermal conductivity coefficient 11.7w/m/k 5.10w/m/k

 

 

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